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Pikachu   

RSE & LGFR RBY
PIKACHU
Item
Light Ball (SA x1.5)
Nature
Timid (+Spd, -Atk)
Ability
Static
EVs
4 HP, 252 Spd, 252 SA
Stats
HP Grass: 212 HP, 131 Atk, 95 Def, 306 Spd, 396 SA, 116 SD
HP Ice: 212 HP, 131 Atk, 96 Def, 305 Spd, 398 SA, 116 SD
Slot 1Slot 2Slot 3Slot 4
ThunderboltSurfHidden Power IceHidden Power GrassSubstitute
MoveEffectTypePwrAcc
     
Notes: HP Grass will take out the likes of Lanturn and Water/Grounds, but otherwise HP Ice seems to be better.

RAICHU
Item
Leftovers/Lum Berry
Nature
Hasty (+Spd, -Def)
Ability
Static
EVs
104 Atk, 152 Spd, 252 SA
Stats
261 HP, 242 Atk, 131 Def, 301 Spd, 279 SA, 196 SD
Slot 1Slot 2Slot 3Slot 4
SubstituteFocus PunchSurfThunderbolt
MoveEffectTypePwrAcc